Synthesis
Mixture | 1 SiO2 : 0.1 SDA : 0.2 NaOH : 0.01 Al2O3 : 5.5 H2O |
SDA | Tetramethylammonium hydroxide |
Temperature | 125.00 °C |
Duration | 7-21 d |
Conditions | convection oven |
Reference |
Ikeda, Oumi, Sano, Momma & Izumi (2011): Inorganic Chemistry, Volume 50, Issue 6, Pages 2294-2301. |
Crystal Structure
Structurally nearly identical materials | None |
Crystal chemically related materials | None |
Chemical composition per unit cell | [(CH3)4N]2[Si10O18(OH)6] |
Lattice parameters of the 2D cell of the layer |
|
Lattice parameters related to the stacking direction |
|
Space group | P2(1) |
XRD reflections representing the 2D cell of the layer |
|
XRD reflections representing the layer-layer distance |
|
Reference |
Ikeda, Oumi, Sano, Momma & Izumi (2011): Inorganic Chemistry, Volume 50, Issue 6, Pages 2294-2301. |
Properties
Density (calculated) | 1.896 g/cm3 |
Condensation product | unknown |
h | k | l | M | 2θ | Icalc | d-hkl |
---|---|---|---|---|---|---|
1 | 0 | 0 | 2 | 9.920 | 38.7 | 8.909 |
0 | 0 | 1 | 2 | 10.163 | 8.3 | 8.697 |
-1 | 0 | 1 | 2 | 13.475 | 53.6 | 6.566 |
1 | 1 | 0 | 4 | 13.816 | 76.8 | 6.405 |
0 | 1 | 1 | 4 | 13.992 | 8.9 | 6.324 |
1 | 0 | 1 | 2 | 14.929 | 19.7 | 5.930 |
-1 | 1 | 1 | 4 | 16.566 | 9.9 | 5.347 |
1 | 1 | 1 | 4 | 17.774 | 14.5 | 4.986 |
0 | 2 | 0 | 2 | 19.253 | 33.2 | 4.607 |
2 | 0 | 0 | 2 | 19.915 | 75.8 | 4.454 |
0 | 0 | 2 | 2 | 20.407 | 39.6 | 4.348 |
-2 | 0 | 1 | 2 | 21.451 | 10.1 | 4.139 |
1 | 2 | 0 | 4 | 21.701 | 13.2 | 4.092 |
-1 | 0 | 2 | 2 | 21.796 | 1.4 | 4.074 |
0 | 2 | 1 | 4 | 21.816 | 1.5 | 4.071 |
. | . | . | . | . | . | |
2 | 1 | 0 | 4 | 22.148 | 0.7 | 4.010 |
0 | 1 | 2 | 4 | 22.593 | 19.6 | 3.932 |
2 | 0 | 1 | 2 | 23.324 | 2.9 | 3.811 |
-2 | 1 | 1 | 4 | 23.545 | 83.1 | 3.776 |
-1 | 2 | 1 | 4 | 23.574 | 77.2 | 3.771 |
1 | 0 | 2 | 2 | 23.643 | 0.0 | 3.760 |
-1 | 1 | 2 | 4 | 23.861 | 45.2 | 3.726 |
1 | 2 | 1 | 4 | 24.450 | 100.0 | 3.638 |
2 | 1 | 1 | 4 | 25.271 | 11.0 | 3.522 |
1 | 1 | 2 | 4 | 25.567 | 66.0 | 3.481 |
-2 | 0 | 2 | 2 | 27.141 | 1.1 | 3.283 |
2 | 2 | 0 | 4 | 27.838 | 8.7 | 3.202 |
0 | 2 | 2 | 4 | 28.199 | 32.2 | 3.162 |
-2 | 1 | 2 | 4 | 28.848 | 10.6 | 3.092 |
-2 | 2 | 1 | 4 | 28.978 | 1.1 | 3.079 |
-1 | 2 | 2 | 4 | 29.239 | 5.7 | 3.052 |
3 | 0 | 0 | 2 | 30.067 | 0.8 | 2.970 |
2 | 0 | 2 | 2 | 30.119 | 5.6 | 2.965 |
2 | 2 | 1 | 4 | 30.418 | 4.9 | 2.936 |
1 | 2 | 2 | 4 | 30.668 | 23.5 | 2.913 |
1 | 3 | 0 | 4 | 30.771 | 7.0 | 2.903 |
-3 | 0 | 1 | 2 | 30.786 | 2.5 | 2.902 |
0 | 0 | 3 | 2 | 30.819 | 8.8 | 2.899 |
0 | 3 | 1 | 4 | 30.854 | 7.7 | 2.896 |
-1 | 0 | 3 | 2 | 31.441 | 3.2 | 2.843 |
3 | 1 | 0 | 4 | 31.629 | 7.1 | 2.827 |
2 | 1 | 2 | 4 | 31.679 | 0.4 | 2.822 |
-1 | 3 | 1 | 4 | 32.152 | 10.4 | 2.782 |
-3 | 1 | 1 | 4 | 32.317 | 20.4 | 2.768 |
0 | 1 | 3 | 4 | 32.349 | 1.1 | 2.765 |
3 | 0 | 1 | 2 | 32.816 | 0.3 | 2.727 |
1 | 3 | 1 | 4 | 32.816 | 2.1 | 2.727 |
-1 | 1 | 3 | 4 | 32.945 | 1.7 | 2.717 |
1 | 0 | 3 | 2 | 33.436 | 5.9 | 2.678 |
-2 | 2 | 2 | 4 | 33.492 | 20.7 | 2.673 |
3 | 1 | 1 | 4 | 34.266 | 0.2 | 2.615 |
-3 | 0 | 2 | 2 | 34.779 | 1.5 | 2.578 |
1 | 1 | 3 | 4 | 34.863 | 0.4 | 2.571 |
-2 | 0 | 3 | 2 | 35.149 | 2.6 | 2.551 |
2 | 3 | 0 | 4 | 35.476 | 0.1 | 2.528 |
0 | 3 | 2 | 4 | 35.766 | 0.2 | 2.509 |
3 | 2 | 0 | 4 | 35.951 | 2.6 | 2.496 |
2 | 2 | 2 | 4 | 35.996 | 20.1 | 2.493 |
-3 | 1 | 2 | 4 | 36.160 | 1.5 | 2.482 |
-2 | 3 | 1 | 4 | 36.400 | 1.2 | 2.466 |
-2 | 1 | 3 | 4 | 36.517 | 2.9 | 2.459 |
-3 | 2 | 1 | 4 | 36.567 | 0.7 | 2.455 |
0 | 2 | 3 | 4 | 36.596 | 2.0 | 2.454 |
-1 | 3 | 2 | 4 | 36.613 | 4.0 | 2.452 |
Atom | x | y | z | Biso | Occ. | |
---|---|---|---|---|---|---|
Si1 | 0.7365 | 0.2500 | -0.0490 | 1.44 | 1.000 | |
Si2 | 0.7580 | 0.0170 | 0.2220 | 1.44 | 1.000 | |
Si3 | 0.2420 | -0.0060 | 0.7850 | 1.44 | 1.000 | |
Si4 | 0.0240 | 0.2540 | 0.7700 | 1.44 | 1.000 | |
Si5 | 0.8113 | 0.2550 | 0.4692 | 1.44 | 1.000 | |
O1 | 0.5920 | 0.2470 | 0.8360 | 1.98 | 1.000 | |
O2 | 0.8850 | 0.2330 | 0.8730 | 1.98 | 1.000 | |
O3 | 0.6020 | -0.0460 | 0.2510 | 1.98 | 1.000 | |
O4 | 0.4010 | 0.0510 | 0.7600 | 1.98 | 1.000 | |
O5 | 0.8820 | 0.9030 | 0.1930 | 1.98 | 1.000 | |
O6 | 0.1230 | 0.1140 | 0.7980 | 1.98 | 1.000 | |
O7 | 0.6510 | 0.2730 | 0.5420 | 1.98 | 1.000 | |
O8 | 0.8130 | 0.1080 | 0.3700 | 1.98 | 1.000 | |
O9 | 0.1770 | 0.8930 | 0.6450 | 1.98 | 1.000 | |
O10 | 0.7320 | 0.1130 | 0.0700 | 1.98 | 1.000 | |
O11 | 0.2450 | 0.8980 | 0.9430 | 1.98 | 1.000 | |
O12 | -0.0470 | 0.2460 | 0.5980 | 1.98 | 1.000 | |
N5 | 0.7360 | 0.7570 | 0.7390 | 2.30 | 1.000 | |
C1 | 0.8690 | 0.8160 | 0.8280 | 2.30 | 1.000 | |
C2 | 0.6950 | 0.8600 | 0.6050 | 2.30 | 1.000 | |
C3 | 0.7650 | 0.6120 | 0.6730 | 2.30 | 1.000 | |
C4 | 0.5970 | 0.7460 | 0.8260 | 2.30 | 1.000 |
User Cell Range (natural numbers 1-5):