Synthesis
Mixture | 1 SiO2 : 0.1-0.3 SDA : 5.3-15.9 H2O |
SDA | Tetraethylammonium hydroxide |
Temperature | 170.00 °C |
Duration | 24-72 h |
Conditions | n/a |
Reference |
Ikeda, Kayamori & Mizukami (2009): Journal of Materials Chemistry, Volume 19, Issue 31, Pages 5518-5525. |
Crystal Structure
Structurally nearly identical materials | None |
Crystal chemically related materials | None |
Chemical composition per unit cell | [(C2H5)4NOH]2 [Si36O68(OH)8] ∙ 12.7 H2O |
Lattice parameters of the 2D cell of the layer |
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Lattice parameters related to the stacking direction |
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Space group | Pnnm |
XRD reflections representing the 2D cell of the layer |
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XRD reflections representing the layer-layer distance |
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Reference |
Ikeda, Kayamori & Mizukami (2009): Journal of Materials Chemistry, Volume 19, Issue 31, Pages 5518-5525. |
Properties
Density (calculated) | 1.865 g/cm3 |
Condensation product | Silica-Ferrierite (zeolite framework type: FER) |
h | k | l | M | 2θ | Icalc | d-hkl |
---|---|---|---|---|---|---|
1 | 0 | 1 | 4 | 7.364 | 1.2 | 11.995 |
0 | 0 | 2 | 2 | 7.575 | 100.0 | 11.662 |
0 | 1 | 1 | 4 | 12.516 | 4.9 | 7.067 |
2 | 0 | 0 | 2 | 12.647 | 2.3 | 6.994 |
1 | 0 | 3 | 4 | 13.018 | 0.2 | 6.795 |
1 | 1 | 0 | 4 | 13.504 | 3.5 | 6.552 |
1 | 1 | 1 | 8 | 14.030 | 0.0 | 6.307 |
2 | 0 | 2 | 4 | 14.758 | 0.7 | 5.998 |
0 | 0 | 4 | 2 | 15.183 | 0.7 | 5.831 |
1 | 1 | 2 | 8 | 15.501 | 1.9 | 5.712 |
0 | 1 | 3 | 4 | 16.507 | 6.5 | 5.366 |
2 | 1 | 0 | 4 | 17.416 | 0.0 | 5.088 |
1 | 1 | 3 | 8 | 17.689 | 0.0 | 5.010 |
2 | 1 | 1 | 8 | 17.829 | 4.7 | 4.971 |
2 | 1 | 2 | 8 | 19.016 | 0.3 | 4.663 |
. | . | . | . | . | . | |
3 | 0 | 1 | 4 | 19.399 | 0.4 | 4.572 |
2 | 0 | 4 | 4 | 19.808 | 14.5 | 4.478 |
1 | 0 | 5 | 4 | 20.050 | 7.3 | 4.425 |
1 | 1 | 4 | 8 | 20.373 | 8.5 | 4.356 |
2 | 1 | 3 | 8 | 20.849 | 9.2 | 4.257 |
3 | 0 | 3 | 4 | 22.215 | 13.4 | 3.998 |
0 | 1 | 5 | 4 | 22.500 | 5.7 | 3.948 |
3 | 1 | 0 | 4 | 22.508 | 5.7 | 3.947 |
3 | 1 | 1 | 8 | 22.832 | 0.1 | 3.892 |
0 | 0 | 6 | 2 | 22.859 | 2.5 | 3.887 |
2 | 1 | 4 | 8 | 23.183 | 1.0 | 3.834 |
1 | 1 | 5 | 8 | 23.392 | 0.0 | 3.800 |
3 | 1 | 2 | 8 | 23.780 | 0.0 | 3.739 |
0 | 2 | 0 | 2 | 23.982 | 1.3 | 3.708 |
1 | 2 | 0 | 4 | 24.823 | 0.1 | 3.584 |
1 | 2 | 1 | 8 | 25.119 | 6.0 | 3.542 |
0 | 2 | 2 | 4 | 25.184 | 19.8 | 3.533 |
3 | 1 | 3 | 8 | 25.285 | 0.1 | 3.519 |
4 | 0 | 0 | 2 | 25.452 | 14.9 | 3.497 |
2 | 1 | 5 | 8 | 25.893 | 10.6 | 3.438 |
1 | 2 | 2 | 8 | 25.989 | 0.5 | 3.426 |
2 | 0 | 6 | 4 | 26.208 | 3.6 | 3.398 |
4 | 0 | 2 | 4 | 26.591 | 8.9 | 3.349 |
1 | 1 | 6 | 8 | 26.644 | 2.6 | 3.343 |
3 | 0 | 5 | 4 | 27.017 | 4.7 | 3.298 |
2 | 2 | 0 | 4 | 27.201 | 0.1 | 3.276 |
3 | 1 | 4 | 8 | 27.262 | 0.2 | 3.269 |
1 | 2 | 3 | 8 | 27.381 | 6.0 | 3.255 |
2 | 2 | 1 | 8 | 27.473 | 0.9 | 3.244 |
1 | 0 | 7 | 4 | 27.497 | 2.9 | 3.241 |
4 | 1 | 0 | 4 | 28.192 | 0.0 | 3.163 |
2 | 2 | 2 | 8 | 28.275 | 1.6 | 3.154 |
4 | 1 | 1 | 8 | 28.456 | 2.5 | 3.134 |
0 | 2 | 4 | 4 | 28.506 | 3.5 | 3.129 |
2 | 1 | 6 | 8 | 28.882 | 0.0 | 3.089 |
1 | 2 | 4 | 8 | 29.226 | 0.0 | 3.053 |
4 | 1 | 2 | 8 | 29.233 | 0.0 | 3.053 |
0 | 1 | 7 | 4 | 29.364 | 0.3 | 3.039 |
2 | 2 | 3 | 8 | 29.568 | 0.4 | 3.019 |
3 | 1 | 5 | 8 | 29.624 | 0.2 | 3.013 |
4 | 0 | 4 | 4 | 29.768 | 0.0 | 2.999 |
1 | 1 | 7 | 8 | 30.066 | 0.1 | 2.970 |
4 | 1 | 3 | 8 | 30.488 | 0.2 | 2.930 |
0 | 0 | 8 | 2 | 30.641 | 0.1 | 2.915 |
3 | 2 | 0 | 4 | 30.787 | 0.0 | 2.902 |
3 | 2 | 1 | 8 | 31.030 | 2.8 | 2.880 |
2 | 2 | 4 | 8 | 31.295 | 0.1 | 2.856 |
1 | 2 | 5 | 8 | 31.453 | 4.3 | 2.842 |
3 | 2 | 2 | 8 | 31.750 | 0.0 | 2.816 |
2 | 1 | 7 | 8 | 32.086 | 1.1 | 2.787 |
4 | 1 | 4 | 8 | 32.171 | 0.0 | 2.780 |
5 | 0 | 1 | 4 | 32.202 | 0.0 | 2.778 |
3 | 1 | 6 | 8 | 32.297 | 1.6 | 2.770 |
3 | 2 | 3 | 8 | 32.918 | 0.6 | 2.719 |
3 | 0 | 7 | 4 | 33.017 | 0.3 | 2.711 |
2 | 0 | 8 | 4 | 33.268 | 0.1 | 2.691 |
0 | 2 | 6 | 4 | 33.370 | 0.0 | 2.683 |
2 | 2 | 5 | 8 | 33.398 | 0.3 | 2.681 |
1 | 1 | 8 | 8 | 33.620 | 0.5 | 2.664 |
1 | 2 | 6 | 8 | 33.997 | 0.1 | 2.635 |
5 | 0 | 3 | 4 | 34.032 | 0.1 | 2.632 |
4 | 1 | 5 | 8 | 34.226 | 0.3 | 2.618 |
5 | 1 | 0 | 4 | 34.231 | 2.5 | 2.617 |
5 | 1 | 1 | 8 | 34.453 | 0.0 | 2.601 |
4 | 0 | 6 | 4 | 34.471 | 0.5 | 2.600 |
3 | 2 | 4 | 8 | 34.495 | 0.2 | 2.598 |
5 | 1 | 2 | 8 | 35.110 | 0.2 | 2.554 |
1 | 0 | 9 | 4 | 35.192 | 0.0 | 2.548 |
3 | 1 | 7 | 8 | 35.222 | 0.0 | 2.546 |
4 | 2 | 0 | 4 | 35.252 | 0.9 | 2.544 |
2 | 1 | 8 | 8 | 35.459 | 0.1 | 2.530 |
4 | 2 | 1 | 8 | 35.468 | 0.0 | 2.529 |
2 | 2 | 6 | 8 | 35.819 | 2.1 | 2.505 |
4 | 2 | 2 | 8 | 36.109 | 0.6 | 2.485 |
5 | 1 | 3 | 8 | 36.183 | 0.0 | 2.481 |
3 | 2 | 5 | 8 | 36.434 | 0.0 | 2.464 |
0 | 3 | 1 | 4 | 36.527 | 0.6 | 2.458 |
4 | 1 | 6 | 8 | 36.599 | 0.1 | 2.453 |
0 | 1 | 9 | 4 | 36.707 | 0.3 | 2.446 |
1 | 2 | 7 | 8 | 36.802 | 0.0 | 2.440 |
1 | 3 | 0 | 4 | 36.899 | 0.6 | 2.434 |
Atom | x | y | z | Biso | Occ. | |
---|---|---|---|---|---|---|
Si1 | 0.0000 | 0.0000 | 0.1731 | 1.50 | 1.000 | |
Si2 | 0.0000 | 0.2937 | 0.2675 | 1.50 | 1.000 | |
Si3 | 0.2030 | 0.9900 | 0.1126 | 1.50 | 1.000 | |
Si4 | 0.2070 | 0.2000 | 0.3072 | 1.50 | 1.000 | |
Si5 | 0.7970 | 0.2090 | 0.6861 | 1.50 | 1.000 | |
O1 | 0.0000 | 0.5000 | 0.2500 | 2.50 | 1.000 | |
O2 | 0.0000 | 0.1780 | 0.2109 | 2.50 | 1.000 | |
O3 | 0.0910 | -0.0040 | 0.1336 | 2.50 | 1.000 | |
O4 | 0.7730 | 0.0040 | 0.6749 | 2.50 | 1.000 | |
O5 | 0.2080 | 0.9740 | 0.0414 | 2.50 | 1.000 | |
O6 | 0.2530 | 0.2430 | 0.2470 | 2.50 | 1.000 | |
O7 | 0.2560 | 0.1700 | 0.1370 | 2.50 | 1.000 | |
O8 | 0.7470 | 0.1830 | 0.8550 | 2.50 | 1.000 | |
O9 | 0.0950 | 0.2410 | 0.3020 | 2.50 | 1.000 | |
O10 | 0.9100 | 0.2450 | 0.6910 | 2.50 | 1.000 | |
N | 0.5100 | 0.2800 | 0.0000 | 8.50 | 0.500 | |
C1A | 0.4900 | 0.1700 | 0.0500 | 8.50 | 0.500 | |
C2A | 0.4500 | 0.4500 | 0.0100 | 8.50 | 0.250 | |
C3B | 0.4700 | 0.5300 | 0.0680 | 8.50 | 0.250 | |
C4B | 0.5170 | 0.9700 | 0.9500 | 8.50 | 0.250 | |
C5A | 0.6100 | 0.3300 | 0.0000 | 8.50 | 0.250 | |
C6B | 0.6240 | 0.4700 | 0.0500 | 8.50 | 0.250 | |
OW1C | 0.0990 | 0.4350 | 0.0210 | 3.50 | 1.000 | |
OW2C | 0.5230 | 0.8440 | 0.4050 | 3.50 | 0.590 |
User Cell Range (natural numbers 1-5):