Synthesis
Mixture | 0-0.1 Al2O3 : 1.0 SDA : 0.25-1.5 NH4 : 0.5 HF : 10-30 H2O |
SDA | 4-Amino-2,2,6,6-tetramethylpiperidine |
Temperature | 170.00 °C |
Duration | 14-28 d |
Conditions | n/a |
Reference |
Schreyeck, Caullet, Mougenel, Guth & Marler (1996): Microporous Materials, Volume 6, Issue 5-6, Pages 259-271. |
Crystal Structure
Comment | The structure data as presented here are based on the non-conventional SG setting: Im. The conventional SG setting is Cm. |
Structurally nearly identical materials | None |
Crystal chemically related materials | None |
Chemical composition per unit cell | (C9H21N2)4 [Si36O76(OH)4] ∙ 8 H2O |
Lattice parameters of the 2D cell of the layer |
|
Lattice parameters related to the stacking direction |
|
Space group | Cm |
XRD reflections representing the 2D cell of the layer |
|
XRD reflections representing the layer-layer distance |
|
Reference |
Marler & Müller (2019): Microporous and Mesoporous Materials, Volume 288, Issue 1 November 2019, Pages 109597. |
Properties
Density (calculated) | 1.912 g/cm3 |
Condensation product | Silica-Ferrierite (zeolite framework type: FER) |
h | k | l | M | 2θ | Icalc | d-hkl |
---|---|---|---|---|---|---|
0 | 2 | 0 | 2 | 6.704 | 100.0 | 13.173 |
1 | 1 | 0 | 4 | 7.156 | 4.0 | 12.343 |
1 | 3 | 0 | 4 | 11.893 | 0.8 | 7.435 |
0 | 1 | 1 | 4 | 12.376 | 1.4 | 7.146 |
2 | 0 | 0 | 2 | 12.661 | 1.8 | 6.986 |
0 | 4 | 0 | 2 | 13.432 | 8.5 | 6.587 |
-1 | 0 | 1 | 2 | 13.467 | 6.8 | 6.570 |
1 | 0 | 1 | 2 | 13.522 | 8.3 | 6.543 |
2 | 2 | 0 | 4 | 14.340 | 2.7 | 6.172 |
-1 | 2 | 1 | 4 | 15.057 | 0.3 | 5.879 |
1 | 2 | 1 | 4 | 15.107 | 0.9 | 5.860 |
0 | 3 | 1 | 4 | 15.616 | 11.9 | 5.670 |
-2 | 1 | 1 | 4 | 17.699 | 4.5 | 5.007 |
2 | 1 | 1 | 4 | 17.783 | 6.2 | 4.984 |
1 | 5 | 0 | 4 | 17.977 | 4.4 | 4.930 |
. | . | . | . | . | . | |
2 | 4 | 0 | 4 | 18.499 | 12.4 | 4.792 |
-1 | 4 | 1 | 4 | 19.065 | 1.7 | 4.651 |
1 | 4 | 1 | 4 | 19.104 | 1.4 | 4.642 |
3 | 1 | 0 | 4 | 19.339 | 0.3 | 4.586 |
-2 | 3 | 1 | 4 | 20.117 | 1.1 | 4.410 |
2 | 3 | 1 | 4 | 20.191 | 3.5 | 4.394 |
0 | 6 | 0 | 2 | 20.207 | 1.9 | 4.391 |
0 | 5 | 1 | 4 | 20.653 | 1.3 | 4.297 |
3 | 3 | 0 | 4 | 21.581 | 2.7 | 4.114 |
-3 | 0 | 1 | 2 | 22.468 | 1.9 | 3.954 |
3 | 0 | 1 | 2 | 22.568 | 4.3 | 3.937 |
-3 | 2 | 1 | 4 | 23.472 | 0.8 | 3.787 |
3 | 2 | 1 | 4 | 23.568 | 0.2 | 3.772 |
2 | 6 | 0 | 4 | 23.917 | 6.7 | 3.718 |
0 | 0 | 2 | 2 | 23.952 | 1.0 | 3.712 |
-2 | 5 | 1 | 4 | 24.267 | 9.1 | 3.665 |
2 | 5 | 1 | 4 | 24.329 | 5.7 | 3.656 |
-1 | 6 | 1 | 4 | 24.362 | 2.9 | 3.651 |
1 | 6 | 1 | 4 | 24.393 | 3.2 | 3.646 |
1 | 7 | 0 | 4 | 24.474 | 3.8 | 3.634 |
0 | 2 | 2 | 4 | 24.899 | 17.6 | 3.573 |
-1 | 1 | 2 | 4 | 24.998 | 4.7 | 3.559 |
1 | 1 | 2 | 4 | 25.058 | 1.5 | 3.551 |
4 | 0 | 0 | 2 | 25.481 | 11.4 | 3.493 |
3 | 5 | 0 | 4 | 25.505 | 11.6 | 3.490 |
-3 | 4 | 1 | 4 | 26.267 | 0.2 | 3.390 |
3 | 4 | 1 | 4 | 26.354 | 1.0 | 3.379 |
4 | 2 | 0 | 4 | 26.377 | 6.8 | 3.376 |
0 | 7 | 1 | 4 | 26.530 | 3.5 | 3.357 |
-1 | 3 | 2 | 4 | 26.792 | 3.4 | 3.325 |
1 | 3 | 2 | 4 | 26.849 | 6.6 | 3.318 |
0 | 8 | 0 | 2 | 27.053 | 1.0 | 3.293 |
-2 | 0 | 2 | 2 | 27.125 | 0.1 | 3.285 |
2 | 0 | 2 | 2 | 27.236 | 0.2 | 3.272 |
0 | 4 | 2 | 4 | 27.559 | 10.5 | 3.234 |
-2 | 2 | 2 | 4 | 27.972 | 0.5 | 3.187 |
2 | 2 | 2 | 4 | 28.081 | 0.4 | 3.175 |
-4 | 1 | 1 | 4 | 28.365 | 0.7 | 3.144 |
4 | 1 | 1 | 4 | 28.472 | 0.3 | 3.132 |
4 | 4 | 0 | 4 | 28.910 | 1.0 | 3.086 |
-2 | 7 | 1 | 4 | 29.471 | 0.3 | 3.028 |
2 | 7 | 1 | 4 | 29.523 | 0.8 | 3.023 |
2 | 8 | 0 | 4 | 29.972 | 0.2 | 2.979 |
-4 | 3 | 1 | 4 | 29.973 | 0.6 | 2.979 |
4 | 3 | 1 | 4 | 30.075 | 0.3 | 2.969 |
-1 | 5 | 2 | 4 | 30.084 | 2.0 | 2.968 |
1 | 5 | 2 | 4 | 30.135 | 1.1 | 2.963 |
-1 | 8 | 1 | 4 | 30.335 | 0.3 | 2.944 |
1 | 8 | 1 | 4 | 30.360 | 0.3 | 2.942 |
-2 | 4 | 2 | 4 | 30.383 | 0.1 | 2.940 |
-3 | 6 | 1 | 4 | 30.396 | 0.3 | 2.938 |
3 | 6 | 1 | 4 | 30.472 | 0.1 | 2.931 |
2 | 4 | 2 | 4 | 30.484 | 0.2 | 2.930 |
3 | 7 | 0 | 4 | 30.513 | 1.2 | 2.927 |
-3 | 1 | 2 | 4 | 30.892 | 0.6 | 2.892 |
3 | 1 | 2 | 4 | 31.041 | 1.8 | 2.879 |
1 | 9 | 0 | 4 | 31.191 | 0.8 | 2.865 |
0 | 6 | 2 | 4 | 31.533 | 0.0 | 2.835 |
5 | 1 | 0 | 4 | 32.188 | 0.2 | 2.779 |
-3 | 3 | 2 | 4 | 32.386 | 0.6 | 2.762 |
3 | 3 | 2 | 4 | 32.529 | 0.2 | 2.750 |
4 | 6 | 0 | 4 | 32.735 | 0.3 | 2.734 |
0 | 9 | 1 | 4 | 32.861 | 0.2 | 2.723 |
-4 | 5 | 1 | 4 | 32.975 | 0.0 | 2.714 |
4 | 5 | 1 | 4 | 33.069 | 0.3 | 2.707 |
5 | 3 | 0 | 4 | 33.630 | 0.1 | 2.663 |
0 | 10 | 0 | 2 | 34.000 | 0.1 | 2.635 |
-2 | 6 | 2 | 4 | 34.058 | 1.1 | 2.630 |
2 | 6 | 2 | 4 | 34.149 | 1.3 | 2.623 |
-5 | 0 | 1 | 2 | 34.204 | 1.0 | 2.619 |
5 | 0 | 1 | 2 | 34.317 | 0.9 | 2.611 |
-1 | 7 | 2 | 4 | 34.486 | 0.1 | 2.599 |
1 | 7 | 2 | 4 | 34.531 | 0.5 | 2.595 |
-5 | 2 | 1 | 4 | 34.895 | 0.3 | 2.569 |
5 | 2 | 1 | 4 | 35.006 | 0.1 | 2.561 |
-4 | 0 | 2 | 2 | 35.164 | 0.3 | 2.550 |
-3 | 5 | 2 | 4 | 35.204 | 0.0 | 2.547 |
-2 | 9 | 1 | 4 | 35.324 | 0.0 | 2.539 |
3 | 5 | 2 | 4 | 35.337 | 0.2 | 2.538 |
4 | 0 | 2 | 2 | 35.341 | 0.4 | 2.538 |
2 | 9 | 1 | 4 | 35.368 | 0.2 | 2.536 |
-3 | 8 | 1 | 4 | 35.445 | 0.4 | 2.531 |
3 | 8 | 1 | 4 | 35.511 | 0.2 | 2.526 |
-4 | 2 | 2 | 4 | 35.838 | 0.4 | 2.504 |
4 | 2 | 2 | 4 | 36.012 | 0.3 | 2.492 |
3 | 9 | 0 | 4 | 36.215 | 0.2 | 2.478 |
5 | 5 | 0 | 4 | 36.363 | 1.2 | 2.469 |
2 | 10 | 0 | 4 | 36.417 | 0.1 | 2.465 |
0 | 1 | 3 | 4 | 36.434 | 0.2 | 2.464 |
0 | 8 | 2 | 4 | 36.441 | 0.7 | 2.464 |
-1 | 10 | 1 | 4 | 36.722 | 0.1 | 2.445 |
1 | 10 | 1 | 4 | 36.744 | 0.2 | 2.444 |
-1 | 0 | 3 | 2 | 36.822 | 0.2 | 2.439 |
1 | 0 | 3 | 2 | 36.886 | 0.2 | 2.435 |
-5 | 4 | 1 | 4 | 36.899 | 0.8 | 2.434 |
Atom | x | y | z | Biso | Occ. | |
---|---|---|---|---|---|---|
SI1 | 0.2111 | 0.3050 | 0.2230 | 1.31 | 1.000 | |
SI6 | -0.1867 | 0.2996 | -0.1940 | 1.31 | 1.000 | |
SI5 | 0.2104 | 0.3080 | 0.8060 | 1.31 | 1.000 | |
SI7 | -0.1952 | 0.2992 | -0.7700 | 1.31 | 1.000 | |
SI2 | 0.0100 | 0.2613 | 0.3070 | 1.31 | 1.000 | |
SI8 | 0.0135 | 0.2679 | -0.2760 | 1.31 | 1.000 | |
SI3 | 0.3110 | 0.3709 | 0.5120 | 1.31 | 1.000 | |
SI9 | -0.2850 | 0.3721 | -0.4870 | 1.31 | 1.000 | |
SI4 | 0.0165 | 0.1815 | 0.0120 | 1.31 | 1.000 | |
O1 | 0.4950 | 0.7472 | 0.0190 | 1.64 | 1.000 | |
O2 | 0.3070 | 0.4293 | 0.5330 | 1.64 | 1.000 | |
O9 | -0.2650 | 0.4309 | -0.4860 | 1.64 | 1.000 | |
O3 | 0.4180 | 0.3485 | 0.5080 | 1.64 | 1.000 | |
O10 | -0.3975 | 0.3603 | -0.4880 | 1.64 | 1.000 | |
O4 | 0.2730 | 0.2554 | 0.2520 | 1.64 | 1.000 | |
O11 | 0.2410 | 0.2491 | 0.7770 | 1.64 | 1.000 | |
O5 | 0.5300 | 0.2798 | 0.3440 | 1.64 | 1.000 | |
O12 | -0.4630 | 0.2876 | -0.3000 | 1.64 | 1.000 | |
O6 | 0.2280 | 0.3248 | 0.0180 | 1.64 | 1.000 | |
O13 | -0.2140 | 0.3084 | 0.0160 | 1.64 | 1.000 | |
O7 | 0.2450 | 0.3518 | 0.3440 | 1.64 | 1.000 | |
O14 | -0.2470 | 0.3393 | -0.3140 | 1.64 | 1.000 | |
O15 | 0.2880 | 0.3346 | 0.6870 | 1.64 | 1.000 | |
O16 | -0.2250 | 0.3502 | -0.6630 | 1.64 | 1.000 | |
O8 | 0.1010 | 0.2971 | 0.2700 | 1.64 | 1.000 | |
O17 | -0.0754 | 0.3056 | -0.2330 | 1.64 | 1.000 | |
O18 | 0.0974 | 0.3078 | 0.7630 | 1.64 | 1.000 | |
O19 | -0.0800 | 0.2962 | -0.7410 | 1.64 | 1.000 | |
C1 | -0.0795 | 1.0672 | -0.4730 | 17.10 | 1.500 | |
C2 | 0.0930 | 1.0908 | -0.4510 | 17.10 | 1.500 | |
C3 | 0.5270 | 0.4529 | 0.7750 | 17.10 | 1.333 | |
C4 | 0.0220 | 1.0472 | -0.5160 | 17.10 | 1.000 | |
N6 | 0.0480 | 1.0000 | -0.4300 | 17.10 | 0.642 | |
N7 | 0.1190 | 1.0000 | 0.0380 | 17.10 | 0.714 | |
C5 | 0.0870 | 1.0000 | -0.7790 | 17.10 | 0.583 | |
C11 | 0.5480 | 1.0736 | 0.7770 | 17.10 | 1.500 | |
C12 | 0.5150 | 1.0478 | 0.5950 | 17.10 | 1.000 | |
C13 | 0.4360 | 1.0856 | 0.5160 | 17.10 | 1.500 | |
C14 | 0.5970 | 1.0483 | 0.4670 | 17.10 | 1.333 | |
C15 | 0.6560 | 1.0000 | 0.4670 | 17.10 | 0.583 | |
N16 | 0.7140 | 1.0000 | 0.3010 | 17.10 | 0.714 | |
N17 | 0.4710 | 1.0000 | 0.6230 | 17.10 | 0.642 | |
OW1 | 0.4160 | 0.5000 | 0.4640 | 34.00 | 0.625 | |
OW2 | 0.7840 | 0.5000 | 0.2030 | 34.00 | 0.625 | |
OW3 | -0.1000 | 0.5000 | 0.6710 | 34.00 | 0.625 | |
OW4 | -0.2340 | 1.0000 | -0.1790 | 34.00 | 0.625 |
User Cell Range (natural numbers 1-5):
No data available